iCloud
Currently I have a lot of photos in the Pictures folder sorted into sub folders. They are not in the Photos App. Can I put them into iCloud without them transferring into the Photos app and if so how please?
iMac 21.5″, macOS 10.13
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If you want pictures folder from default finder location and drag and drop to iCloud.com - not possible .
See the article https://support.apple.com/en-in/guide/mac-help/mchlp1143/10.14/mac/10.14
System
This folder contains the macOS operating system. You can’t change the name or location of the System folder or the items within it.